How Initiators Influence Free Radical Polymerization Results
Free-radical polymerization turns small alkenes into high-molecular-weight chains within seconds, yet the initiator you choose dictates whether the product is a brittle film at 25 °C or an elastomer that stretches 800 %. A 0.05 wt % shift in initiator concentration can halve the molar mass or double the gel content, so mastering initiator behavior…